In this example the amount of work done by the person is 30J, this is also the amount of electrical potential energy that is possessed by all three charges together. The electrical potential (not energy) is the amount of energy per unit of charge.
(http://regentsprep.org/Regents/physics/phys03/apotdif/calc.gif)
At the original position of the charges they have no energy, so they also have no electrical potential or 0 volts. Once they are pulled apart, they have have an electrical potential of 10 volts. We could say that the electrical potential difference from one point to the other is 10 volts.
Keep in mind that the electrical potential describes the amount of energy per unit of charge. This means that when one of the charges is released, the electric field will do 10 Joules of work on the charge so it will have a kinetic energy of 10 Joules the instant before it strikes the negative charge.